Carbon and its Compounds (PYQs)
Carbon and its Compounds (PYQs)
1. Draw electron dot structure of NH3 molecule. Predict the total no. of bonds around N-atom.
OR
A molecule of ammonia has the formula NH3. Predict the total number of bonds present around nitrogen atom.
View AnswerAns. It has 3 bonds around N-atom.
2. Why covalent compounds are poor conductors of electricity?
View AnswerAns. It is because covalent compounds do not form ions.
3. Which element exhibits the property of catenation to maximum extent and why?
View Answer4. Explain why carbon generally forms compounds by covalent bonds or do not form ionic compounds.
OR
Give reason why carbon neither forms C4+ cations nor C4– anions but form covalent compounds which are bad conductors of electricity and have low melting and boiling points.
OR
Carbon has four electrons in its valence shell. How does carbon attain stable configuration?
View AnswerAns. Carbon since it forms strong covalent bond, due to smaller atomic size.
5. Why are most carbon compounds poor conductors of electricity?
View AnswerAns. Carbon compounds form covalent bonds/do not dissociate into ions/do not have charged particles (ions).
6. Define catenation.
View AnswerAns. The property of self-linking of atoms of an element through covalent bonds in order to form straight chain, branched chains or cyclic chains of different sizes is called catenation.
7. Covalent compounds have low melting and boiling point. Why?
View AnswerAns. It is because they have weak van der Waal’s forces of attraction between molecules therefore have low melting and boiling points.
8. How are covalent bonds formed?
View AnswerAns. Covalent bonds are formed by equal sharing of electrons.
9. Give a test that can be used to confirm the presence of carbon in a compound. With a valency of 4, how is carbon able to attain noble gas configuration in its compounds?
View AnswerAns. – Burn compound in air/ oxygen; Gas evolved turns lime water milky
– By sharing its four valence electrons with other elements.
10. The number of carbon compounds is more than those formed by all other elements put together. Justify the statement by giving two reasons.
View Answer– Due to self-linking ability of carbon/catenation
– Since carbon has a valency of four it can form bonds with four other atoms of carbon or atoms of some other mono-valent element.
– Due to small size of carbon it forms very strong and (or) stable bonds with other elements
11. What are covalent compounds? Why are they different from ionic compounds? List their three characteristic properties.
View AnswerAns. Those compounds which are formed by equal sharing of electrons are called covalent compounds. They are different from ionic compounds since ionic compounds are formed by transfer of electrons from one atom to another.
Properties:
(i) They have low melting and boiling points.
(ii) They do not conduct electricity in molten state and in aqueous solution.
(iii) They are mostly insoluble in water but soluble in organic solvents except glucose, sugar, urea, ethyl alcohol, etc.
12. (a) Explain why carbon forms covalent bond? Give two reasons for carbon forming a large number of compounds.
View AnswerAns. Carbon has electronic configuration 2, 4. It could gain four electrons forming C-4 anion or lose 4 electrons to form C+4 cation. Both are not possible due to energy considerations. Carbon overcome this problem by sharing electrons and forming covalent compounds. Two reasons for forming large number of compounds:
(1) Catenation (2) Tetra valency
(b) Explain the formation of ammonia molecule.
View AnswerAns. Formation of NH3 molecule Three hydrogen atoms each share their 1 electron with nitrogen to form three covalent bonds and make an ammonia molecule (NH3).
13. Carbon, a member of group 14, forms a large number of carbon compounds estimated to be about three million. Why is this property not exhibited by other elements of this group? Explain.
View AnswerAns. Carbon shows the property of catenation. It forms strong covalent bonds with other atoms of carbon forming long straight, branched and closed chain compounds.
Carbon is smallest in size in group 14 with tatravalency, it can form double as well as triple bonds, therefore, it can show property of catenation to maximum extent and forms 3 million compounds other elements cannot show property of catenation to this extent due to larger size form weaker covalent bond and cannot form double or triple bonds.
14. (i) Explain the formation of calcium chloride with the help of electron dot structure. (At numbers: Ca = 20; Cl = 17)
View AnswerAns.
(ii) Why do ionic compounds not conduct electricity in solid state but conduct electricity in molten and aqueous state?
View AnswerAns. Ionic compounds do not conduct in solid state due to absence of free ions but they conduct electricity in molten and aqueous state due to presence of free ions.
15. Write the molecular formula of benzene and state the number of double bonds in its structure.
View AnswerAns. C6H6. It has three double bonds
16. What is homologous series?
View AnswerAns. It is a series of organic compounds having same functional group and similar chemical properties.
17. Write the general formula of alkenes. Write the name of the simplest alkene.
View AnswerAns. CnH2n, Ethene is simplest alkene.
18. Write the next homologue of each of the following: (i) C2H4 (ii) C4H6
View Answer(i) C3H6, (ii) C5H8
19. Write the molecular formula of alcohol derived from butane.
View AnswerAns. C4H9OH or CH3CH2CH2CH2OH (Butan-1-ol)
20. Write the name and formula of second member of homologous series with general formula CnH2n+2
View AnswerAns. C2H6, Ethane
21. Write the name and formula of second member of homologous series having general formula CnH2n–2.
View AnswerAns. C3H4, Propyne
22. The formula of citric acid is shown below:
State the name of —COOH functional group in citric acid.
View AnswerAns. Carboxylic acid
23. The molecular formula of ‘A’ is C10H18 and ‘B’ is C18H36. Name the homologous series to which they belong.
View AnswerAns. ‘A’ belongs to Alkynes, ‘B’ belongs to Alkenes.
24. Write the molecular formula of first two members of homologous series having functional group Cl.
View AnswerAns. The general formula of the compounds having –Cl functional group is CnH2n + 1Cl. Its two members are:
(i) CH3Cl (ii) CH3 – CH2 – Cl
25. Write the molecular formula of the 2nd and the 3rd member of the homologous series whose first member is methane (CH4).
View AnswerAns. (i) CH3CH3 (Ethane); where n is 2
(ii) CH3CH2CH3 (Propane); where n is 3
26. Write the electron dot diagram of ethane (C2H6) molecule.
View AnswerAns. There are 7 covalent bonds.
27. Write the number of covalent bonds in propane, C3H8.
View AnswerAns. There are 10 covalent bonds.
28. Write the number of covalent bonds in the molecule of butane (C4H10).
View AnswerAns. There are 13 covalent bonds.
29. Name a cyclic unsaturated carbon compound.
View AnswerAns. Benzene is cyclic unsaturated carbon compound.
30. Which of the following is not observed in a homologous series? Give reason for your choice
(a) Change in chemical properties
(b) Difference in -CH2 and 14u molecular mass
(c) Gradation in physical properties
(d) Same functional group
View AnswerAns. It does not occur due to the presence of the same functional group.
31. The general formula of three compounds A, B and C is CnH2n. ‘B’ has the highest boiling point and ‘C’ has the lowest boiling point.
(i) Mention the type of compounds A, B and C.
View AnswerAns. Unsaturated hydrocarbons with double bonds.
(ii) Which of these has minimum number of carbon atoms?
View AnswerAns. ‘C’ has minimum boiling point, so ‘C’ has minimum no. of C-atoms.
(iii) Name the homologous series to which A, B and C belong
View AnswerAns. Alkene
32. Select alkenes and alkynes from the following:
C2H4, C3H4, C2H2, C4H8
Write their structural formula also
View AnswerC2H4 and C4H8 are alkenes, C3H4 and C2H2 are alkynes.
33. What is homologous series of carbon compounds? Give an example and list its three characteristics.
View AnswerAns. The series of organic compounds having same functional group and similar chemical properties is called homologous series. For example,
Characteristics:
- Each successive member differs by CH2 unit.
- They have gradation in physical properties.
- They have similar chemical properties due to presence of same functional group.